If all your loan payments are the same size, then they have to exceed the interest on the loan. If they didn't, then you'd never pay off the loan, as the principal would grow rather than shrink.
Even so, compounding still matters. First, compounding at a frequency greater than that which you make payments will mean that you pay compounded interest with each payment. For example, if you pay monthly but your interest is compounded daily, your monthly payment will include your daily compounded interest. But even if the compounding frequency is less than the payment period, it still matters because it affects the principal. A quick example:
Principal Interest Payment
$1000 $3 $202
$801 $2.40 $202
$601.40 $1.80 $202
$401.20 $1.20 $202
$200.40 $0.60 $201
This is $1000 borrowed at 3.6% annually which is a monthly rate of .3%, compounded monthly. Now let's see what the same loan looks like without compounding.
Principal Interest Payment Accrued
$1000 $3 $202 $3
$798 $2.39 $202 $5.39
$596 $1.79 $202 $7.18
$394 $1.18 $202 $8.36
$192 $0.57 $200.93 $8.93
Not a huge difference with so little principal for such a short term, but measurable.
You might try to avoid compounding on a loan where interest is added to the principal with variable payments. Payments would look like
Principal Interest Payment
$1000 $3 $203
$800 $2.40 $202.40
$600 $1.80 $201.80
$400 $1.20 $201.20
$200 $0.60 $200.60
But note how we're back to paying $9 of interest, not the $8.93 of simple interest. Worse, the higher payments in the early periods are with more valuable current dollars while the lower future payments are in less valuable future dollars. This is the exact opposite of what you'd want to do.
The only way to avoid compounding is to pay off the entire loan before the second time that interest is charged. Otherwise it is still there, making the loan more expensive.